Please use this identifier to cite or link to this item: https://er.nau.edu.ua/handle/NAU/38230
Title: Polymer modified bitumen
Other Titles: Бітуми, модифіковані полімерами
Битумы, модифицированные полимерами
Authors: Pyshyev, Serhiy
Gunka, Volodymyr
Prysiazhnyi, Yuriy
Keywords: Polymer modified bitumen
elastomer
thermoplastic elastomer
reactive polymer
thermoplastic
coumarone-indene resin
phenol formaldehyde resin
Issue Date: 2019
Publisher: National Aviation University
Abstract: The reasons for bitumen modification were analysed since bitumen is a main binder used at road coatings construction, including airports and airdromes. The main ways of bitumen modification by polymers were examined. Positive and negative aspects of the usage of different polymer modifiers (elastomers, thermoplastic elastomers, reactive polymers, thermoplastics) were analysed. Author’s main achievements are described in the sphere of bitumen modification by polymeric compounds produced at by-product-coke plants: coumarone-indene and phenol-cresol-formaldehyde resins.
У статті розглянуто основні способи модифікації бітумів полімерами. Встановлено, що використання полімерних модифікаторів дає змогу покращити експлуатаційні властивості бітумів. Проаналізовано позитивні і негативні аспекти використання різних груп полімерних модифікаторів (еластомери, термоеластопласти, реактопласти, термопласти). Показано досягнення кафедри хімічної технології переробки нафти та газу Національного університету «Львівська політехніка» в галузі модифікації бітумів полімерами: інден-кумароновою, нафтополімерними, фенол формальдегідними і епоксидними смолами.
В статье рассмотрены основные способы модификации битумов полимерами. Установлено, что использование полимерных модификаторов позволяет улучшить эксплуатационные свойства битумов. Проанализированы положительные и отрицательные аспектыиспользования различных групп полимерных модификаторов (эластомеры, термоэластопласты, реактопласты, термопласты). Показано достижения кафедры химической технологии переработки нефти и газа Национального университета «Львовская политехника» в области модификации битумов полимерами: инден-кумароновой, нефтеполимерной, фенолформальдегидной и эпоксидной смолами.
Description: 1. Bitumen asphalt, total productin – for all countries [Electronic reference]. – Access mode: http://www.factfish.com/statistic/bitumen%20asphalt,%20total%20productin. 2. Bitumen asphalt, exports (thousand metric tons) – for all countries [Electronic reference]. – Access mode: http://www.factfish.com/statistic/bitumen%20asphalt%2C%20exports. 3. Bitumen asphalt, imports (thousand metric tons) – for all countries [Electronic reference]. – Access mode: http://www.factfish.com/statistic/bitumen%20asphalt%2C%20imports. 4. Galdina V. Modified bitumen: a tutorial / V. Galdina. – Omsk: SibADI, 2009. – 228 pp. 5. Kishchinsky S.V. Physical and mechanical properties of bitumen, modified by a complex modifier Polyd / S.V. Kishchinsky // Vestn. HNADU. – 2008. – Issue 40. – P. 28–32. 6. Zhu Jiqing. Polymer modification of bitumen: Advances and challenges / Jiqing Zhu, Björn Birgisson, Niki Kringos // European Polymer Journal. – 2014. – Vol. 54. – P. 18–38. 7. Tarasov R.V. Modification of bitumens by polymers / R.V. Tarasov, L.V. Makarova, A.A. Kadomtseva // Modern scientific researches and innovations [Electronic reference]. – 2014. – № 5. – Access mode: http://web.snauka.ru/en/issues/2014/05/34687. 8. Valentová Т. Impact of Asphalt Ageing on the Activity of Adhesion Promoters and the Moisture Susceptibility / Tereza Valentová, Jan Altman, Jan Valentin // Transportation Research Procedia. – 2016. – Vol. 14. – P. 768–777. 9. Impact of Ageing and the Stability of Adhesion Additive on Moisture Susceptibility and Adhesion / [Hamidi Abdul Aziz, Meor Othman Hamzah, Fauziah Ahmad еt al.]. // Applied echanics and Materials. – 2015. – Vol. 802. – P. 309–314. 10. Plasticizing additives from phthalic anhydride residue and 2-ethylhexanol residue for improvement of properties of road petroleum bitumens / G.N. Kinzyagulova, A.S. Alyabev, N.G. Evdokimova, I.A. Sultanbekova // Electronic scientific journal «Oil and Gas Business» [Electronic reference]. – 2009. – №1. – Access mode: http://ogbus.ru/eng/authors/Kinzyagulova/Kinzyagulova_1.pdf. 11. Mousavi S.M. Enhancement of rheological and mechanical properties of bitumen using styrene acrylonitrile copolymer / Seyed Mojtaba Mousavi, Mohammad Farsi, Mahdi Azizi // Journal of Applied Polymer Science. – 2015. – Vol. 132 (17). – P. 41875. 12. Petroleum Bitumen Modified by Polymer Materials for Asphalt Concrete Surfacing with Improved Operational Performance / P. S. Belyaev, D. L. Polushkin, P. V. Makeev, V. A. Frolov // Transactions TSTU. – 2016. – Vol. 22 (2). – P. 264. 13. Muneraa J.C. Polymer modified bitumen: Optimization and selection / J.C. Muneraa, E.A. Ossa // Materials and Design. – 2016. – Vol. 62. – P. 91–97. 14. Package of polyfunctional modifiers (pfm) for production of bitumen and bitumen materials of wide assortment with high operational properties [Electronic reference] – Access mode: http://www.econf.rae.ru/article/4548. 15. BulatovićV.O. Effect of polymer modifiers on the properties of bitumen / Vesna Ocelic ́Bulatovic ́, Vesna Rek and Kristina JurkasˇMarkovic // Journal of Elastomers and Plastics. – 2014. – Vol. 46. – P. 448–469. 16. Vasavi S. Efect of natural rubber on the properties of bitumen and bituminous mixes / S. Vasavi, D. Rani // International Journal of Civil Engineering and Technology. – 2014. – Vol. 5 (10). – P. 9–21. 17. Keyf S. The modification of bitumen with reactive ethylene terpolymer, styrene butadiene styrene and variable amounts of ethylene vinyl acetate / S. Keyf // Research on Chemical Intermediates. – 2015. – Vol. 41 (3). – P. 1485–1497. 18. Vichitcholchai N. Modification of Asphalt Cement by Natural Rubber for Pavement Construction / Nopparat Vichitcholchai, Jaratsri Panmai and Nuchanat Na-Ranong // Rubber thai journal. – 2012. – Vol. 1. – P. 32–39. 19. Review on the Effect of Crumb Rubber Addition to the Rheology of Crumb Rubber Modified Bitumen / [Mohd Rasdan Ibrahim, Herda Yati Katman, Mohamed Rehan Karim et al.]. // Advances in Materials Science and Engineering. – 2013. – Vol. 2013. – Article ID 415246. 20. Review on Using Crumb Rubber in Reinforcement of Asphalt Pavement / Nuha Salim Mashaan, Asim Hassan Ali, Mohamed Rehan Karim, Mahrez Abdelaziz // Scientific World Journal. – 2014. – Vol. 2014. – P. 214612. 21. A study of crumb rubber modified bitumen used in South Africa / Georges A.J. Mturi, Johan O'Connell, Salah E. Zoorob, Morris De Beer // Road Materials and Pavement Design. – 2014. – Vol. 15 (4). – P. 774–790. 22. Polymer modified bitumen: Rheological properties and structural characterization / [Cesare Oliviero Rossi, Assunta Spadafora, Bagdat Teltayev et al.]. // Colloids and Surfaces A Physicochemical and Engineering Aspects. – 2015. – Vol. 480. – P. 390–397. 23. Effect of styrene–butadiene–styrene copolymer modification on properties of Saudi bitumen / Abdulrahman A. Al-Rabiah, Omar Y. Abdelaziz, Enrique M. Montero, Mohamed S. Aazam // Petroleum Science and Technology. – 2016. – Vol. 34 (4). – P. 321–327. 24. Choice of polymer-bitumen binders for cast asphalt concrete mixes / S. V. Vorontsov, N. V. Maidanova, A. M. Syroezhko, S. N. Ivanov // Russian Journal of Applied Chemistry. – 2012. –Vol. 85 (2) – P. 323–330. 25. Karton [Electronic reference]. – Access mode: http://www.kraton.com. 26. Total [Electronic reference]. – Access mode: http://www.total.com/en. 27. Eni [Electronic reference]. – Access mode: https://www.eni.com/en_IT/products.page. 28. Dynasol group [Electronic reference]. – Access mode: http://www.dynasolelastomers.com. 29. Modified Phenol-Formaldehyde Resins and their Application in Bitumen-Polymeric Mixtures / [Galyna Strap, Olena Astakhova, Olexander Lazorko et al.]. // Chemistry & Chemical Technology. – 2013. – Vol. 7 (3). – P. 279–287. 30. Rheological Properties and Performance Evaluation of Phenol Formaldehyde Modified Bitumen / M.Çubuk, M.Gürü, M. Çubuk, D. Arslan // Journal of Materials in Civil Engineering. – 2014. – Vol. 26 (6). – P. 04014015. 31. Abd El Rahman A. Modification of local asphalt with epoxy resin to be used in pavement / A.M.M. Abd El Rahman, M. EL-Shafie, S.A. El Kholy // Egyptian Journal of Petroleum. – 2012. – Vol. 21 (2). – P. 139–147. 32. Ivashkiv O. Structure and Application of ED-20 Epoxy Resin Hydroxy-Containing Derivatives in Bitumen-Polymeric Blends / [O. Ivashkiv, O. Astakhova, O. Shyshchak et al.]. // Chemistry & Chemical Technology. – 2015. – Vol. 9. – № 1. – P. 69–76. 33. Monomethacrylate derivative of ED-24 epoxy resin and its application / [Oksana Iatsyshyn, Olena Astakhova, Olena Shyshchak et al.]. // Egyptian Journal of Petroleum. – 2013. – Vol. 7 (1). – P. 73–77. 34. Binder Design for Asphalt Mixes with Reduced Temperature: EVA Modified Bitumen and its Emulsions / Avido Yuliestyan, Antonio Abad Cuadri, Moisés García-Morales, Pedro Partal // Transportation Research Procedia. – 2016. – Vol. 14. – P. 3512–3518. 35. Bulatovic V. Rheological properties and stability of ethylenevinylacetatepolymer-modified bitumen / Vesna Ocelić Bulatović, VesnaRek, KristinaJurkaš Marković // Polymer Engineering & Science. – 2013. – Vol. 53 (11). – P. 2276–2283. 36. Brozyna D. Modification of asphalt binders by polyethylene-type polymers / Dariusz Brożyna, Karol J. Kowalskia // Journal of Building Chemistry. – 2016. – Vol. 1. – P. 37–41. 37. Rheological Properties of Polyethylene and Polypropylene Modified Bitumen / Noor Zainab Habib, Ibrahim Kamaruddin, Madzalan Napiah, Isa Mohd Tan // International Journal of Civil, Environmental, Structural, Construction and Architectural Engineering. – 2010. – Vol. 4 (12). – P. 381–385. 38. Al-Ameri M. Modification of Residual Bitumen from orhovytska Oil by Butonal Polymeric Latexes / Mohammad Al-Ameri, Oleh Grynyshyn and Yuriy Khlibyshyn // Chemistry & Chemical Technology. – 2013. – Vol. 7 (3). – P. 323–326. 39. Onischenko A. Research on Properties of Bitumen Modified with Polymers Used for Asphalt Concrete Pavement on Bridges / Arthur Onischenko, Mykolay Kuzminets, Sergey Aksenov // Teka. Commission of motorization and energetics in agriculture. – 2014. – Vol. 14 (4). – P. 113–118. 40. Research of influencing of parameters of preparation of the bitumen modified by polymeric latex of butonal ns 104, on property of travelling bitumen / V.Mozgovoy, A.Besarab, A.Prudkiy, V. Smolianets // Bulletin of Kharkov National Automobile and Highway University. – 2006. – Vol. 34–35. 41. Basf [Electronic reference]. – Access mode: https://www.basf.com. 42. Dupont [Electronic reference]. – Access mode: http://www.dupont.com. 43. Petroleum resins for bitumens modification / Oleg Grynyshyn, Michael Bratychak, Volodymyr Krynytskiy, Volodymyr Donchak. // Chemistry & ChemicalTechnology. – 2008. – Vol. 2 (1). – P. 47–53. 44. Grynyshyn O. Production of Bitumen Modified by Petroleum Resins on the Basis of Tars of Ukrainian Oils / Oleg Grynyshyn, Olena Astakhova, Taras Chervinskyy // Chemistry & Chemical Technology. – 2010. – Vol. 4 (3). – P. 241–246. 45. Functional petroleum resins based on pyrolysis by-products and their application for bitumen modification / [M. Bratychak, O. Grynyshyn, O. Astakhova et al.]. // Ecological Chemistry and Engineering. – 2010. – Vol. 17 (3). – P. 309–315. 46. Production of Indene-coumarone Resins as Bitumen Modifiers / [Serhiy Pyshyev, Yuriy Grytsenko, Nazar Danyliv et al.]. // Petroleum & Coal. – 2015. – Vol. 57. – Issue 4. – P. 303. 47. Using bitumen emulsions based on oxidated, distillation and modified oxidated bitumens for Slurry Seal production / [Serhiy Pyshyev, Yuriy Grytsenko, Serhiy Solodkyy et al.]. // Chemistry & Chemical Technology. – 2015. – Vol. 9 (3). – P. 359–366. 48. The production of indene-coumarone resins for modification of oil road-bitumen / S.V. Pyshyev, Yu.B. Gritsenko, I.Yе. Nykulyshyn, Z.Ya. Gnativ // Journal of Coal Chemistry. – 2014. – № 5–6. – P. 41–48. 49. Demchuk Y. Obtaining of the modifiers of road bitumen from phenol fraction of coal tar / Y. Demchuk, V. Gunka, S. Pyshyev, M. Bratychak // Uglekhim. Zh. – 2017. – №5. – P.2 3–28. 50. Effect of Phenol-Cresol-Formaldehyde Resin on Adhesive and Physico-Mechanical Properties of Road Bitumen / [Y. Demchuk, Iu. Sidun, V. Gunka et al.]. // Chemistry & Chemical Technology. – 2018. – Vol. 12 (4). – P. 456. 51. Production of Indene-coumarone Resins as Bitumen Modifiers / [S.Pyshyev, Y.Grytsenko, H.Bilushchak et al.]. // Petroleum and Coal. – 2015. – №4. – P. 303–314. 52. The production of indene-koumarone resins for modification of oil road-bitumen / S.V.Pyshyev, Y.B.Gritsenko, I.Y.Nykulyshyn, Z.Y. Gnativ // Journal of Coal Chemistry. – 2014. – № 5–6. – P. 41–48. 53. D.V. Miroshnichenko. Predicting the yield of coke and its byproducts on the basis of elementary and petrographic analysisn / D.V.Miroshnichenko, M.B. Golovko // Coke and Chemistry. – 2014. – №3. – P. 32–43. 54. Predicting the yield of coking byproducts on the basis of elementary and petrographic analysis of the coal batch / M.B. Golovko, I.D. Drozdnik, D.V. Miroshnichenko, Y.S. Kaftan // Coke and Chemistry. – 2014. – № 6. – P. 204–214. 55. Gunka V. Lignite oxidative desulphurization. Notice 2: effects of process parameters / Volodymyr Gunka, Serhiy Pyshyev // International Journal of Coal Science & Technology.– 2015.– Vol. 2 (3). – Р. 196–201. 56. Gunka V. Technology of Oxidative Desulphurization of Lignite / Volodymyr Gunka, Serhiy Pyshyev // Petroleum & Coal. –2015. – Vol. 57. – Issue 6. – P. 696–704. 57. Lignite oxidative desulphurization. Notice 1. Process condition selection / Volodymyr Gunka, Serhiy Pyshyev // International Journal of Coal Science & Technology. – 2014. – Vol. 1. – Issue 1. – Р. 62–69. 58. Toroptseva A.M. Laboratory session on chemistry and technology of high-molecular compounds / A.M. Toroptseva, K.M. Belogorodskaya, V.M. Bondarenko. – Chemistry: L., 1972. – P. 416.
URI: http://er.nau.edu.ua/handle/NAU/38230
Appears in Collections:Вибрані аспекти забезпечення хіммотологічної надійності техніки

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